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Air pollution maps for specific situations

Maps for the surface concentrations of air pollutants, and for the depositions have been created based on the results from the modelling system WRF-CMAQ. The model output is in terms of hourly values for more than 20 pollutants, meteorological variables and deposition parameters, so it becomes important to select representative time periods for their visualization.

Selection of meteorological situations

The selected periods for the purposes of the project represent 3 categories:

The periods have different duration, from 4 to 10 days. The synoptic situation for each period is briefly outlined. The maps are presented as animated image files, so that the temporal variation for a given period can be followed.
Three different types of maps are shown – respectively for surface concentrations (ozone, nitrogen oxide, nitrogen dioxide, sulphur dioxide, particulate matter with diameter < 10 µm and (PM10) particulate matter with diameter < 2.5 µm (PM2.5)), the dry deposition of nitrogen dioxide, ozone, sea salt aerosols and PM10, and the wet depositions of ozone, sea salt aerosols and PM10. The sea salt aerosols are estimated as the sum of chlorine (Cl) and sodium (Na) aerosols with d < 10µm.

1. Dry periods, followed by rains with low pH-values (pH less or around 5)

1a. August: 8–15.08 (predominantly dry) + 16-17.08 (rain in Burgas about 30 lm-2 and in Ahtopol – 10 lm-2). The anticyclone conditions in the dry period are associated with high summer temperatures, well developed breeze circulations along the coast. The following rainy period is associated with southwestern intrusion of air masses and the passage of a cold frontal system from southwest towards northeast.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

1b. September: 8–13.09 (dry) + 14-18.09 (rain mainly in Ahtopol – about 5 lm-2 in total). The dry period is in low-gradient pressure conditions over the country, the rainy period is associated with the passage of a frontal system from west towards east.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

2. Dry periods followed by rains with high pH-values (pH around 6.5)

2a. June: 01–03.06 (relatively dry) + 04-05.06 (rain Burgas – 10 lm-2 and more in Ahtopol – about 39 lm-2 in total). The first part of the period is characterized by relatively cold weather with short precipitations over the country. The following rainy period is associated with the passage of an African cyclone over Southern Bulgaria, bringing moderate to intense rains especially in the region.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

2b. July-Aug: 26–31.07 (dry) + 01-02.08 (rains with low intensity - Burgas – about 3 lm-2, Ahtopol - 1 lm-2). The first part of the period is characterized by the passage of a frontal system and cyclone from west towards east over Bulgaria. However, the cross-border region remains without precipitations. The following rainy period is associated with the passage of a frontal system of a cyclone moving from the western part of the Balkan Peninsula.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

3. Rainy periods, with intense rains, or flooding in southeastern Bulgaria

3a. July: 15-17.07 (local flooding in Southeastern Bulgaria). A cyclone passing from west to east is resident over the country in the days before the period, bringing intensive rains in the western Bulgaria. In the days 15-17.07., the cyclone is moving over eastern Bulgaria. Measured pH values in Ahtopol and Burgas are below 5.5.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

3b. July: 19-25 July (with intense rains on 23-24 .07. in southeastern Bulgaria and in northern Turkey). The measured precipitation on 24.07 is 22 lm-2 in Ahtopol, in Burgas the rain quantity is much smaller – around 6 lm-2).

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

3c. September: 02-03.09 (rain in the Turkish part of the region) + 05-07.09 (rains in southeastern Bulgaria with flooding in Sozopol). The situation is caused by the passage of a Mediterranean cyclone, bringing intensive rains all over the country. Measured pH-values in Ahtopol and Burgas are in the range 5-6.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

3d. October: 23-31.10 (140 lm-2 Ahtopol rain in the period on 25-27 Oct). The situation is characterized by the passage of a Mediterranean cyclone, which remains blocked by a high pressure system situated to the east (over the Caspian Sea). Intensive rains in southern Bulgaria, storm conditions with high waves and strong winds along the seaside at Ahtopol. 24h sums of rain quantity at the seacoast are between 50 and 160 lm-2). Measured pH-values in Ahtopol are acidic (below 5.6), in Burgas – alkaline (about 6.4).

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

4. Dry autumn – periods with temperature inversions favorable for high air pollution

4a. November: 1-10.11. The first two days (1-2.11.) are characterized by anticyclonic type of autumn weather with low clouds and fogs in the valleys, on 6.11 a cyclone from west is passing over the country bringing clouds and rains in western and central Bulgaria. By the end of the period (10.11.) the flow is light from southwest, foggy conditions along the seaside.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt

4b. November: 23 – 29.11. A slowly moving Mediterranean cyclone is passing from west to east over the country on 24.11. In its rear part the flow is cold leading to decrease in the surface temperatures.

Ozone concentration O3
Nitrogen Oxide concentration NO
Nitrogen Dioxide concentration NO2
Sulphur concentration SO2
Concentration of particulate matter with diameter < 10 µm (PM10)
Concentration of particulate matter with diameter < 2.5 µm (PM2.5)

Dry deposition of NO2
Dry deposition of O3
Dry deposition of PM10
Dry deposition of sea salt

Wet deposition O3
Wet deposition of PM10
Wet deposition of sea salt